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  1. 防災科研関係論文

Instrumentation and Method Development for On-Site Analysis of Helium Isotopes

https://nied-repo.bosai.go.jp/records/4434
https://nied-repo.bosai.go.jp/records/4434
f3ec6460-ff45-4538-a411-0124b0af2204
Item type researchmap(1)
公開日 2023-03-30
タイトル
言語 en
タイトル Instrumentation and Method Development for On-Site Analysis of Helium Isotopes
言語
言語 eng
著者 Kirk R. Jensen

× Kirk R. Jensen

en Kirk R. Jensen

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Toshinobu Hondo

× Toshinobu Hondo

en Toshinobu Hondo

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Hirochika Sumino

× Hirochika Sumino

en Hirochika Sumino

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Michisato Toyoda

× Michisato Toyoda

en Michisato Toyoda

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抄録
内容記述タイプ Other
内容記述 Helium isotope determination may be useful in measuring volcanic activity and issuing earlier warnings of possible eruptions. A method is presented for measuring the He-3/He-4 ratio in a gas sample using a multiturn time-of-flight mass spectrometer "infiTOF". In contrast to conventional waveform averaging, peaks are determined by counting ion pulses from each time-of-flight trigger. Samples were also measured by conventional magnetic-sector mass spectrometry for comparison. Magnetic sector results were used to designate a standard for infiTOF measurement and to calculate a ratio for each sample measured by infiTOF. Mass assignment error for ultrapure He-3(+) standard was 4.30 X 10(-5) Da. Mass assignment error of He-4(2+) and He-3(+) for sample cylinders was 3.00 X 10(-8) Da and 2.25 X 10(-4) Da, respectively. Abundance ratios determined by infiTOF were found to be within 2% of the abundance ratios determined by magnetic-sector mass spectrometry. Mass drift was <50 X 10(-6) Da over 10 h. Sample flow rate was not found to affect the results as long as the reference sample was analyzed under the same conditions. Results indicate that the infiTOF system may he a viable tool for measuring helium isotopes, which may eventually lead to earlier warnings of volcanic activity.
言語 en
書誌情報 en : ANALYTICAL CHEMISTRY

巻 89, 号 14, p. 7535-7540
出版者
言語 en
出版者 AMER CHEMICAL SOC
ISSN
収録物識別子タイプ EISSN
収録物識別子 1520-6882
DOI
関連識別子 10.1021/acs.analchem.7b01299
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