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  1. 防災科研関係論文

Experimental petrology of the 1991-1995 Unzen dacite, Japan. Part II: Cl/OH partitioning between hornblende and melt and its implications for the origin of oscillatory zoning of hornblende phenocrysts

https://nied-repo.bosai.go.jp/records/4696
https://nied-repo.bosai.go.jp/records/4696
7d9d8e1e-a08b-452b-8e33-34cdf9b103ee
Item type researchmap(1)
公開日 2023-03-30
タイトル
言語 en
タイトル Experimental petrology of the 1991-1995 Unzen dacite, Japan. Part II: Cl/OH partitioning between hornblende and melt and its implications for the origin of oscillatory zoning of hornblende phenocrysts
言語
言語 eng
著者 Hiroaki Sato

× Hiroaki Sato

en Hiroaki Sato

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Francois Holtz

× Francois Holtz

en Francois Holtz

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Harald Behrens

× Harald Behrens

en Harald Behrens

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Roman Botcharnikov

× Roman Botcharnikov

en Roman Botcharnikov

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Setsuya Nakada

× Setsuya Nakada

en Setsuya Nakada

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抄録
内容記述タイプ Other
内容記述 High-temperature-pressure experiments were carried out to determine the chlorine-hydroxyl exchange partition coefficient between hornblende and melt in the 1992 Unzen dacite. Cl in hornblende and melt was analyzed by electron microprobe, whereas OH in hornblende and melt was calculated assuming anion stoichiometry of hornblende and utilizing the dissociation reaction constant for H2O + O = 2(OH) in water-saturated melt, respectively. The partition coefficient strongly depends on the Mg/(Mg + Fe) ratio of hornblende, and is expressed as In K1 = (Cl/OH)hb/(Cl/OH)melt = 2・ 37 - 4・6[Mg/(Mg + Fe)]hb at 2-3kbar and 800-850°C. The twofold variation in Cl content in the oscillatory zoned cores of hornblende phenocrysts in the 1991-1995 dacite cannot be explained by the dependence of the Cl/OH partition coefficient on the Mg/(Mg + Fe) hb ratio, and requires c. 80% variation of the Cl/OH ratio of the coexisting melt. Available experimental data at 200 MPa on Cl/OH fractionation between fluid and melt suggest that c. 1・ 2-1・8 wt % degassing of water from the magma can explain the required 80% variation in the Cl/OH ratio of the melt. The negative correlation between Al content and Mg/(Mg + Fe) ratio in the oscillatory zoned cores of the hornblende phenocrysts is consistent with repeated influx and convective degassing of the fluid phase in the magma chamber. c Oxford University Press 2004
All rights reserved.
言語 en
書誌情報 en : Journal of Petrology

巻 46, 号 2, p. 339-354, 発行日 2005-02
ISSN
収録物識別子タイプ ISSN
収録物識別子 0022-3530
DOI
関連識別子 10.1093/petrology/egh078
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