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  1. 防災科研関係論文

Hydrous fluid as the growth media of natural polycrystalline diamond, carbonado: Implication from IR spectra and microtextural observations

https://nied-repo.bosai.go.jp/records/5503
https://nied-repo.bosai.go.jp/records/5503
9a975499-9d5e-4844-819b-2876f7321a01
Item type researchmap(1)
公開日 2023-03-30
タイトル
言語 en
タイトル Hydrous fluid as the growth media of natural polycrystalline diamond, carbonado: Implication from IR spectra and microtextural observations
言語
言語 eng
著者 Hidemi Ishibashi

× Hidemi Ishibashi

en Hidemi Ishibashi

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Hiroyuki Kagi

× Hiroyuki Kagi

en Hiroyuki Kagi

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Haruko Sakuai

× Haruko Sakuai

en Haruko Sakuai

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Hiroaki Ohfuji

× Hiroaki Ohfuji

en Hiroaki Ohfuji

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Hirochika Sumino

× Hirochika Sumino

en Hirochika Sumino

Search repository
抄録
内容記述タイプ Other
内容記述 Carbonado, a variety of natural polycrystalline diamond whose origin remains unknown, differs notably in the properties from common diamonds of mantle origin. In this study, infrared spectroscopic and microscopic analyses were conducted on carbonado from the Central African Republic. Stepwise heating followed by infrared spectroscopic measurements indicated that liquid H2O is enclosed within diamond single crystals in carbonado. Transmission electron microscope observation revealed a negative crystal that is interpreted as a primary fluid inclusion in a diamond single crystal. Observations by field-emission scanning electron microscope and electron backscatter diffraction analysis show an absence of lattice preferred orientation of diamond crystals, {111} growth steps along grain boundaries, and the crystal-size distribution of diamond similar to those of crystals formed in liquid media. In addition, the redox conditions of carbonado formation is inferred to be similar to 3 log units below the quartz-magnetite-fayalite buffer, which is the prevailing condition in cratonic upper mantle. These lines of evidence suggest that the carbonado crystallized in C-O-H fluid, supporting the hypothesis of a mantle-depth origin of carbonado.
言語 en
書誌情報 en : AMERICAN MINERALOGIST

巻 97, 号 8-9, p. 1366-1372, 発行日 2012-08
出版者
言語 en
出版者 MINERALOGICAL SOC AMER
ISSN
収録物識別子タイプ ISSN
収録物識別子 0003-004X
DOI
関連識別子 10.2138/am.2012.4097
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